Causes of Foam Formation
(1)Use of surfactants: Surfactants, or surface-active agents, can contribute to foam formation due to their ability to reduce surface tension and stabilize bubbles.
(2)Use of high molecular weight compounds: Certain high molecular weight compounds, such as polymers, can contribute to foam formation due to their surface-active properties.
(3)Inherent foam-forming capability: Some substances have inherent foam-forming properties, but their rate of foam formation is higher than their ability to defoam.
(4)Mechanical agitation in viscous systems: In systems with high viscosity, such as during production or processing involving stirring or mixing, the entry of air can lead to bubble formation.
(5)Gas generation during chemical reactions: The occurrence of chemical reactions in a system can result in the generation of gas molecules, which is sometimes referred to as degassing or gas absorption process.
Why Defoaming?
(1)Prevention of material overflow: Foam can cause the overflow of reaction materials from the reaction vessel, resulting in wastage of raw materials and reducing production capacity.
(2)Improved collision between raw materials: Insufficient collision between raw materials due to foam can prolong the reaction cycle.
(3)Preservation of product quality: Foam formation can lead to a decline in product quality by trapping impurities or interfering with desired chemical reactions.
(4)Prevention of operational hindrances: The generation of foam can disrupt normal production processes, causing operational difficulties.
II. Defoaming Mechanism
The defoaming mechanism is as follows:
Defoamers have a low surface tension, which allows them to easily enter and spread within the liquid film. They reduce the surface tension of the liquid film, causing it to gradually thin out and become unevenly stressed. As a result, the liquid film loses its self-healing capability and eventually ruptures.
III. Classification, Characteristics, and Composition of Defoamers
Classification:
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